web services can only be invoked by HTTP. While Service or a WCF component can be invoked by any protocol and any transport type. Second web services are not flexible. But Services are flexible. If you make a new version of the service then you need to just expose a new end point. So services are agile and which is a very practical approach looking at the current business trends.
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What is the difference WCF and Web services?
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Rajesh Goswami
18-Nov-2010